On the Importance of Clar Structures of Polybenzenoid Hydrocarbons as Revealed by the π-Contribution to the Electron Localization Function

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On the Importance of Clar Structures of Polybenzenoid Hydrocarbons as Revealed by the π-Contribution to the Electron Localization Function

The degree of -electron (de)localization and aromaticity of a series of polybenzenoid hydrocarbons (PBHs) has been analyzed through the π-contribution to the electron localization function (ELFπ), calculated at the B3LYP/6-311G(d,p) hybrid density functional theory level. The extent of -electron delocalization in the various hexagons of a PBH was determined through analysis of the bifurcation...

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On the Importance of Clar Structures of Polybenzenoid Hydrocarbons as Revealed by the pi-Contribution to the Electron Localization Function

The degree of -electron (de)localization and aromaticity of a series of polybenzenoid hydrocarbons (PBHs) has been analyzed through the π-contribution to the electron localization function (ELFπ), calculated at the B3LYP/6-311G(d,p) hybrid density functional theory level. The extent of -electron delocalization in the various hexagons of a PBH was determined through analysis of the bifurcation...

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ژورنال

عنوان ژورنال: Symmetry

سال: 2010

ISSN: 2073-8994

DOI: 10.3390/sym2031653